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Synthesis and absolute stereochemistry of cis- and trans-1,2-indandiols: metabolites of indene and 2-indanone

โœ Scribed by Imuta, Mitsuru; Ziffer, Herman


Book ID
126809505
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
464 KB
Volume
43
Category
Article
ISSN
0022-3263

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Rearrangement of 1,2-divinyl-1,2-cyclohexanediol (I) was shown by Coda, et al (1) to give l-bicyclo[5.3.O]decen-2-one (II). We had made the ssme observation independently (2), but had also found that under milder conditions 7-hydroxybicyclo[5.3,0] decsn-2-one (III) can be isolated in good yield. In