Syntheses, Structures, and Reactivities of Homometallic Rare-Earth-Metal Multimethyl Methylidene and Oxo Complexes
✍ Scribed by Jianquan Hong; Prof. Dr. Lixin Zhang; Xiaying Yu; Meng Li; Dr. Zhengxing Zhang; Dr. Pengzhi Zheng; Dr. Masayoshi Nishiura; Prof. Dr. Zhaomin Hou; Prof. Dr. Xigeng Zhou
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 328 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0947-6539
No coin nor oath required. For personal study only.
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The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual µ 2 ,η 4 :η 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc
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