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Rare Earth Metal Boryl Complexes: Synthesis, Structure, and Insertion of a Carbodiimide and Carbon Monoxide

✍ Scribed by Dr. Shihui Li; Dr. Jianhua Cheng; Dr. Yanhui Chen; Dr. Masayoshi Nishiura; Prof. Dr. Zhaomin Hou


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
327 KB
Volume
50
Category
Article
ISSN
0044-8249

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✍ Hans W. Görlitzer; Michael Spiegler; Reiner Anwander 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 316 KB 👁 2 views

The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual µ 2 ,η 4 :η 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc