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Syntheses of three stable isotope-labeled ethylcyclopropanes

✍ Scribed by John E. Baldwin; Edward J. O'Neil

Publisher
John Wiley and Sons
Year
2009
Tongue
French
Weight
182 KB
Volume
52
Category
Article
ISSN
0022-2135

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✦ Synopsis

Abstract

Three stable isotope‐labeled ethylcyclopropanes have been synthesized in preparation for a mechanistic study of its fragmentation to methane and butadiene. Two tactical innovations have been used to deal with practical synthetic challenges posed by the very limited solubility of methylmagnesium iodide in tetrahydrofuran and the high volatility and high tendency to form aerosols characteristic of ethylcyclopropane. Copyright © 2009 John Wiley & Sons, Ltd.

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