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Syntheses of ( R )- and ( S )-2- and 6-Fluoronorepinephrine and ( R )- and ( S )-2- and 6-Fluoroepinephrine: Effect of Stereochemistry on Fluorine-Induced Adrenergic Selectivities

✍ Scribed by Lu, Shou-fu; Herbert, B.; Haufe, Günter; Laue, Klaus Wilhelm; Padgett, William L.; Oshunleti, O.; Daly, John W.; Kirk, Kenneth L.

Book ID
126288687
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
297 KB
Volume
43
Category
Article
ISSN
0022-2623

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ChemInform Abstract: Syntheses of (R)- a
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✍ Shou-fu Lu; B. Herbert; Guenter Haufe; Klaus Wilhelm Laue; William L. Padgett; O 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 40 KB

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The title compounds were prepared via two efficient routes. The first sequence utilized a diastereospecific triflate alkylation in the key bond forming step while the second method relied on a novel intramolecular Mitsunobu reaction to set the required stereochemistry. Many pharmaceutical agents co