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Syntheses of exo-3,8-dioxatricyclo[3.2.1.02,4]octane and 4,7-dioxatricyclo[3.2.1.03,6]octane and the relative basicities of their ethereal moieties

✍ Scribed by le Drian, Claude; Vogel, Pierre

Book ID: 126298352
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 450 KB
Volume: 58
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00060a060

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The interaction of formally nonconjugated p-orbital systems has been observed in ultraviolet spectra &.g., changes in n + v\* \* and II + II transition energies and intensities for C=C-C-C=0 structures (2) ) as well as in increased rates of carbonium ion reactions (=.g., solvolysia of homoallylic st