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Syntheses, crystal structures and properties of two unusual pillared-layer 3d–4f Ln–Cu heterometallic coordination polymers

✍ Scribed by Le-Qing Fan; Ji-Huai Wu; Yun-Fang Huang

Book ID
113758398
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
998 KB
Volume
184
Category
Article
ISSN
0022-4596

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✍ Le-Qing Fan; Yuan Chen; Ji-Huai Wu; Yun-Fang Huang 📂 Article 📅 2011 🏛 Elsevier Science 🌐 English ⚖ 884 KB

Two new 4d-4f Ln-Ag heterometallic coordination polymers, {[Ln 3 Ag 5 (IN) 10 (H 2 O) 7 ] Á 4(ClO 4 ) Á 4(H 2 O)} n (Ln ¼ Eu (1) and Sm (2), HIN ¼ isonicotinic acid), have been synthesized under hydrothermal conditions by reactions of Ln 2 O 3 , AgNO 3 , HIN and HClO 4 , and characterized by element