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Syntheses, crystal structures and physical properties of two unusual 4d–4f heterometallic coordination polymers

✍ Scribed by Guang-Xiang Liu; Hong Zhou; Xiao-Chun Zha; Chun-You Zhang; Yan Wang; Sadafumi Nishihara; Xiao-Ming Ren

Book ID
113642524
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
769 KB
Volume
387
Category
Article
ISSN
0020-1693

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Two new 4d-4f Ln-Ag heterometallic coordination polymers, {[Ln 3 Ag 5 (IN) 10 (H 2 O) 7 ] Á 4(ClO 4 ) Á 4(H 2 O)} n (Ln ¼ Eu (1) and Sm (2), HIN ¼ isonicotinic acid), have been synthesized under hydrothermal conditions by reactions of Ln 2 O 3 , AgNO 3 , HIN and HClO 4 , and characterized by element