Hydrothermal Synthesis, Crystal Structure and Characterization of a Novel 3D Pillared-Layer 3d–4f Lanthanum-Copper Heterometallic Coordination Polymer
✍ Scribed by Le-Qing Fan; Yuan Chen; Ji-Huai Wu; Yun-Fang Huang
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 370 KB
- Volume
- 21
- Category
- Article
- ISSN
- 1053-0495
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Self-assembly of Cd(NO 3 ) 2 with o-phthalic acid monopotassium salt (KHphth) in the presence of ethylenediamine (en) produced a new heterometallic coordination polymer [CdK 2 (phth) 2 (en) 0.5 (H 2 O)] n (1). Single-crystal X-ray analyses reveal that it crystallizes in a monoclinic space group P2 1
An exploration of the mixed-ligand system under hydrothermal condition, has led to the isolation of a 3-D Single-crystal X-ray analyses reveal that it crystallizes in the triclinic space group P-1, a = 8.807(4) Å, b =11.139(6) Å, c = 11.291(5) Å, α=75.337( 7), β = 73.584(5), γ= 66.795(5)°. The Cu І