𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Synthesis, characterization and crystal structure of a novel 3-D copper(II) polymer with bent N-containing ligand

✍ Scribed by Fumin Wang

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
216 KB
Volume
43
Category
Article
ISSN
0232-1300

No coin nor oath required. For personal study only.

✦ Synopsis

An exploration of the mixed-ligand system under hydrothermal condition, has led to the isolation of a 3-D

Single-crystal X-ray analyses reveal that it crystallizes in the triclinic space group P-1, a = 8.807(4) Å, b =11.139(6) Å, c = 11.291(5) Å, α=75.337( 7), β = 73.584(5), γ= 66.795(5)°. The Cu ІІ ions are linked into an extended 2-D grid net via mp molecules. Further these layers are united together through the bridging L to form a 3-D structure, which exhibits a new 4-connected topological network.

📜 SIMILAR VOLUMES

Synthesis, Crystal Structures, and Magne
Synthesis, Crystal Structures, and Magnetic Properties of Two New 1D Copper(II) Coordination Polymers Containing Fumarate(−2) and Chelating N,N′-Donor as Ligands
✍ Sudipta Dalai; Partha Sarathi Mukherjee; Guillaume Rogez; Talal Mallah; Michael  📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 164 KB 👁 2 views

Two new polynuclear complexes of Cu II , [Cu 2 (fum)(µ-OH)(bpy) 2 (H 2 O)](NO 3 )•2H 2 O (1) (fum = fumarate dianion, bpy = 2,2Ј-bipyridine) and [Cu(fum)(tmen)]•2H 2 O (2) (tmen = N,N,NЈ,NЈ-tetramethylethane-1,2-diamine), have been synthesized and structurally characterized by X-ray crystallography.

Synthesis, characterization and crystal
Synthesis, characterization and crystal structure of a novel 2D Cu(I) complex with flexible ligand
✍ Jianqiang Liu; Yaoyu Wang; Weihong Zhang; Juncheng Jin; Mei Zhang; Qizhen Shi 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 167 KB 👁 1 views

## Abstract An exploration of the Cu(I)‐L system under hydrothermal conditions, has led to the isolation of a novel framework [Cu(I)(L)]~n~ (**1**) (L = bis(3,3‐dimethyl‐4,4‐dihydro‐1H‐pyrazol‐4‐yl)methane). Single‐crystal X‐ray analysis reveals that it crystallizes in the monoclinic, space group C

Synthesis, characterization and crystal
Synthesis, characterization and crystal structure of a novel 2D Ni(II) complex with malate
✍ Weiping Wu; Jianqiang Liu; Fengchun Zeng; Yu Wu 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 205 KB 👁 1 views

## Abstract An exploration of the nickel‐ malate‐bpa system under hydrothermal conditions, has led to the isolation of a novel framework {[Ni(Hmal)(bpa)]·2.5H~2~O}~n~ (**1**) (Hmal = malate dianion, bpa = 1,2‐bi(4‐pyridyl)ethane). Single‐crystal X‐ray analyses reveal that it crystallizes in the ort