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Syntheses, Crystal Structures, and Properties of New Layered Alkali-Metal Molybdenum(VI) Methylphosphonates: Cs2(MoO3)3PO3CH3 and Rb2(MoO3)3PO3CH3

โœ Scribed by Harrison, William T. A.; Dussack, Laurie L.; Jacobson, Allan J.


Book ID
127173986
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
656 KB
Volume
34
Category
Article
ISSN
0020-1669

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Synthesis, Structure, and Properties of
โœ William T.A. Harrison; Laurie L. Dussack; Allan J. Jacobson ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 290 KB

Synthetic Tl 2 (MoO 3 ) 3 PO 3 CH 3 is built up from infinite sheets of distorted octahedral MoO 6 groups, sharing vertices. These octahedral layers are ''capped'' by P-CH 3 entities (as tetrahedral methylphosphonate PO 3 CH 2ุŠ 3 groups) on one face of each Mo/O sheet. Interlayer thallium cations pr