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Hydrothermal Synthesis and Characterization of New Pillared Layered Ethylenediphosphonates of Molybdenum(VI), A 2 [Mo 2 O 5 (O 3 PCH 2 CH 2 PO 3 )] (A = NH 4 , Tl, Cs, Rb) and K(H 3 O)[Mo 2 O 5 (O 3 PCH 2 CH 2 PO 3 )]

✍ Scribed by Rao, K. Prabhakara; Vidyavathy, ; Minimol, M. P.; Vidyasagar, K.

Book ID
121378679
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
202 KB
Volume
43
Category
Article
ISSN
0020-1669

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This paper describes the syntheses of three transition metal diphosphonate compounds: n made up of corner-sharing ZnO 6 octahedra and CPO 3 tetrahedra, which are further connected by tetramers of edge-sharing NaO 6 octahedra, forming a three-dimensional open-framework structure. Compound 2 shows a