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Syntheses, characterization and luminescence of Pt–M (M = Re, Ru, Gd) heteronuclear complexes with 5-ethynyl-2,2′-bipyridine

✍ Scribed by Hai-Bing Xu; Li-Yi Zhang; Zhong-Ning Chen


Book ID
118448864
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
298 KB
Volume
360
Category
Article
ISSN
0020-1693

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✍ Ding-Xian Jia; Jie Deng; Qian-Xin Zhao; Yong Zhang 📂 Article 📅 2007 🏛 Elsevier Science 🌐 English ⚖ 309 KB

Two new lanthanide thioantimonates, [Pr(en) 3 (H 2 O)(l 2 -SbS 4 )] and [Gd(en) 4 ]SbS 4 AE0.5en (en = ethylenediamine), were synthesized using the solvothermal method by reacting LnCl 3 , Sb and S in en at 160 °C. The crystal structure of 1 consists of a one-dimensional [Pr(en) 3 (H 2 O)(l 2 -SbS 4