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Synthesis, structures and properties of two novel charge-transfer complexes with the ratio of ferrocenyl:POM of 1:1, (Bu4N)[CpFeCpCH2N(C2H5)3][M6O19] (M = Mo, W)

✍ Scribed by Haisheng Xu; Lei Zhang; Zuoxi Li; Xuemei Liu; Huaiming Hu; Ganglin Xue


Book ID
113913987
Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
879 KB
Volume
12
Category
Article
ISSN
1293-2558

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In situ synthesis, structural characteri
✍ Yunlong Fu; Hui Lu πŸ“‚ Article πŸ“… 2008 πŸ› Elsevier Science 🌐 English βš– 382 KB

A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU