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Palladium(II) complexes with o-aryl substituted 1,1′-bis(phosphino)ferrocenes [Fe(η5-C5H4PR2)2Pd(NCMe)n](OTf)2 (R = o-MeOC6H4, o-MeC6H4, o-PriC6H4, C6F5): Synthesis, structure and catalytic properties in methoxycarbonylation of ethylene

✍ Scribed by Alexander M. Kalsin; Nikolai V. Vologdin; Tat’yana A. Peganova; Pavel V. Petrovskii; Konstantin A. Lyssenko; Fedor M. Dolgushin; Oleg V. Gusev

Book ID
108189152
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
219 KB
Volume
691
Category
Article
ISSN
0022-328X

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In situ synthesis, structural characteri
In situ synthesis, structural characterization and luminescent property of a novel hybrid solid with twofold interpenetrating (4,6)-connected topology [{(Cu4I4)2H2O}{Cu6(mtz)6}]n (Hmtz = 3,5-dimethyl-1,2,4-triazole)
✍ Yunlong Fu; Hui Lu 📂 Article 📅 2008 🏛 Elsevier Science 🌐 English ⚖ 382 KB

A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU