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Syntheses and structures of three new scandium selenites: Sc2(SeO3)3·H2O, Sc2 (SeO3)3·3H2O and CsSc3(SeO3)4 (HSeO3)2·2H2O

✍ Scribed by Magnus G. Johnston; William T.A. Harrison

Book ID
108195182
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
536 KB
Volume
177
Category
Article
ISSN
0022-4596

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[Y(HSeO3)(SeO3)(H2O)]·H2O
[Y(HSeO3)(SeO3)(H2O)]·H2O
✍ Harrison, William T. A. 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 425 KB

The title compound, aqua(hydrogen trioxoselenato)(trioxoselenato)yttrium(III) monohydrate, which is isostructural with its samarium(III) and neodymium(III) analogues, contains YO~8~, SeO~3~ and HSeO~3~ coordination polyhedra, which fuse together by corner- and edge-sharing, resulting in a layered st