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Zemannite-type Selenites: Crystal structures of K2[CO2(SeO3)3] · 2H2O and K2[Ni2(SeO3)3] · 2H2O

✍ Scribed by M. Wildner

Publisher
Springer
Year
1993
Tongue
English
Weight
937 KB
Volume
48
Category
Article
ISSN
1438-1168

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Co2+in trigonal fields of oxygen based s
Co2+in trigonal fields of oxygen based structures: Electronic absorption spectra of buetschliite-type K2Co(SeO3)2, K2Co2(SeO3)3and zemannite-type K2Co2(SeO3)3· 2H2O
✍ M. Wildner; K. Langer 📂 Article 📅 1994 🏛 Springer-Verlag 🌐 English ⚖ 851 KB

Polarized single crystal absorption spectra, in the spectral range 40 000-5 000 cm-1, were obtained on Co 2+ in trigonally distorted octahedral oxygen fields of buetschliite-type K2Co(SeO3) 2 (I), KzCoz(SeO3) a (II) and zemannite-type K2Co2(SeOa)3.2H20 (III). Site symmetries of Co 2+ are 3m (Dad) in