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Syntheses and crystal structures of two structurally diverse cobalt complexes constructed from 5-hydroxyl-1,3-benzenedicarboxylates

✍ Scribed by Hong-Yin He; Yi-Li Zhou; Yan Hong; Long-Guan Zhu

Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
211 KB
Volume
737
Category
Article
ISSN
0022-2860

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✦ Synopsis

benzenedicarboxylic acid, 4,4 0 -bipyZ4,4 0 -bipyridine), were synthesized using different starting materials and solvents. Compound 1 possesses hydrogen-bonded 3D networks encapsulating 1D covalently bonded infinite [Co(4,4 0bipy)(H 2 O) 4 ] 2C chain. Compound 2 shows a 2D architecture and free 4,4 0 -bipy and DMF molecules fill in the channels of the extended 3D hydrogen bonding network as guest molecules.

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