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Secondary Synthesis of Two Cobalt Complexes by the Use of 5-Sulfosalicylate and 1,10-Phenanthroline and Their Crystal Structures

✍ Scribed by Sai-Rong Fan; Long-Guan Zhu


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
241 KB
Volume
23
Category
Article
ISSN
0256-7660

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Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,