Secondary Synthesis of Two Cobalt Complexes by the Use of 5-Sulfosalicylate and 1,10-Phenanthroline and Their Crystal Structures
β Scribed by Sai-Rong Fan; Long-Guan Zhu
- Publisher
- John Wiley and Sons
- Year
- 2005
- Tongue
- English
- Weight
- 241 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0256-7660
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract A mononuclear Cu(II) complex with mixed ligands, formulated as [Cu(hypydc)(dmp)]Β·H~2~O (hypydc=4βhydroxypyridineβ2,6βdicarboxylate, dmp=2,9βdimethylβ1,10βphenanthroline), was synthesized and well characterized by single crystal Xβray diffraction analysis, as well as spectroscopic (IR, U
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OHΒ±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Γ , b = 107.105(3)Β°,