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Synthesen in der Lumiflavinreihe II

✍ Scribed by P. Hemmerich; H. Erlenmeyer

Publisher
John Wiley and Sons
Year
1957
Tongue
German
Weight
485 KB
Volume
40
Category
Article
ISSN
0018-019X

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✦ Synopsis

Abstract

Starting from lumiflavine and its 2‐thio‐analogue, the leukoflavine nucleus was obtained and stabilized by reductive acylation. The acyl‐leuko‐compounds seem to exhibit the possibility of substitution reactions in 2‐ and 4‐positions. Several new lumiflavines were obtained, e. g. 4‐thiolumiflavine and 2‐desoxylumiflavine. The latter shows rather peculiar oxido‐reductive properties which are discussed.

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