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Synthese von 1α-Hydroxycholecalciferol. Vorläufige Mitteilung

✍ Scribed by Andor Fürst; Ludvik Labler; Werner Meier; Karl-Heinz Pfoertner

Publisher: John Wiley and Sons
Year: 1973
Tongue: German
Weight: 180 KB
Volume: 56
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19730560528

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

1α‐hydroxycholesterol (4a) was synthesized from cholesterol and transformed via its diacetyl derivative 4b into 1α, 3β‐diacetoxycholesta‐5, 7‐diene (6b). Irradiation of the ring‐B‐diene 6b followed by thermal isomerization and saponification gave 1α‐hydroxycholecalciferol (7).

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