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Nickel-katalysierte Synthese von α-Nornicotin-Derivaten. Vorläufige Mitteilung

✍ Scribed by Heinz Peter; Dieter Reinehr

Publisher
John Wiley and Sons
Year
1978
Tongue
German
Weight
144 KB
Volume
61
Category
Article
ISSN
0018-019X

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✦ Synopsis

Nickel‐catalysed Synthesis of α‐Nornicotines

Schiff's bases 1 and butadiene generally co‐oligomerize on nickel catalysts to yield octatrienyl‐substituted amines 2 and octadienyl‐substituted imines 3.

Schiff's bases 4 and 5, on the other hand, react with 1, 3‐dienes to give new [3+2]‐cycloadducts 6. In addition to the appropriately functionalized α‐nornicotine derivatives some higher oligomers are formed.

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