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Synthese und Konformation von Hexahydro-isochino[3,2-a][2]benzazepinen des B-Homoberbin-Typs

✍ Scribed by Meise, Werner ;Zlotos, Darius ;Jansen, Martin ;Zoche, Nicola

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
886 KB
Volume
1995
Category
Article
ISSN
0947-3440

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✦ Synopsis

Synthesis and Conformation of Hexahydro‐isoquino[3,2‐a][2]benzazepines of the B‐Homoberbine Type

The two‐step synthesis of the hexahydro‐isoquino[3,2‐a][2]‐benzazepines („B‐homoberbines”︁) 4b‐e is described. The main and some further products of the Bischler‐Napieralski reaction of hydroxyamide 3c were isolated and identified. The conformation of the B‐homoberbines was investigated by X‐ray analysis, spectroscopic methods and dehydrogenation with mercury(II) acetate.

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