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Synthese speziell substituierter 1-Azaadamantane

✍ Scribed by Dr. Nikolaus Risch; Wolfgang Saak


Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
93 KB
Volume
94
Category
Article
ISSN
0044-8249

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## Abstract Ausgehend von 7‐Oxobicyclo[2.2.1]heptan‐1‐carbonylchlorid **(3)** wurde Bicyclo[2.2.0]hexan‐1‐carbonsäure **(9)** durch Hunsdiecker‐Abbau und Favorskii‐Umlagerung dargestellt. Die Umwandlung von **9** in 1‐Methoxybicyclo[2.2.0]hexan **(15)** über das Methylketon **12** und Acetat **13**