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Symmetry rules and reaction mechanisms of Ziegler–Natta catalysts

✍ Scribed by John A Ewen

Book ID
104423544
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
256 KB
Volume
128
Category
Article
ISSN
1381-1169

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Ethylene polymerization reactions with Z
Ethylene polymerization reactions with Ziegler–Natta catalysts. I. Ethylene polymerization kinetics and kinetic mechanism
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Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r

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Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit a number of features that differentiate them from polymerization reactions of ␣ olefins: (1) a relatively low ethylene reactivity, (2) markedly higher polymerization rates in the presence of ␣ olefins, (3) a high reaction or