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Ethylene oligomerization and chain growth mechanisms with Ziegler-Natta catalysts

✍ Scribed by Kissin, Y. V.; Nowlin, T. E.; Mink, R. I.

Book ID
120412949
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
773 KB
Volume
26
Category
Article
ISSN
0024-9297

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πŸ“œ SIMILAR VOLUMES

Ethylene polymerization reactions with Z
Ethylene polymerization reactions with Ziegler–Natta catalysts. III. Chain-end structures and polymerization mechanism
✍ Y. V. Kissin; R. I. Mink; T. E. Nowlin; A. J. Brandolini πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 306 KB πŸ‘ 2 views

Ethylene polymerization reactions with many Ziegler-Natta catalysts exhibit a number of features that differentiate them from polymerization reactions of ␣ olefins: (1) a relatively low ethylene reactivity, (2) markedly higher polymerization rates in the presence of ␣ olefins, (3) a high reaction or

Ethylene polymerization reactions with Z
Ethylene polymerization reactions with Ziegler–Natta catalysts. I. Ethylene polymerization kinetics and kinetic mechanism
✍ Y. V. Kissin; R. I. Mink; T. E. Nowlin πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 287 KB πŸ‘ 1 views

Kinetics of ethylene homopolymerization reactions and ethylene/1-hexene copolymerization reactions using a supported Ziegler-Natta catalyst was carried out over a broad range of reaction conditions. The kinetic data were analyzed using a concept of multicenter catalysis with different centers that r