## Abstract Reaction of an isocyanide with an electron‐poor aromatic aldehyde in the presence of silica nanoparticles (silica NP; __ca.__ 42 nm) proceeds smoothly at room temperature to afford 2‐hydroxyacetamide derivatives in high yields (__Scheme 1__ and __Table 1__).
Supramolecular capping-ligand effect of lamellar silica mesostructures for the one-pot synthesis of highly dispersed ZnO nanoparticles
✍ Scribed by Fernández, Lorenzo; Garro, Núria; Morales, José Manuel; Burguete, Pedro; Latorre, Julio; Guillem, Carmen; Beltrán, Aurelio; Beltrán, Daniel; Amorós, Pedro
- Book ID
- 120435563
- Publisher
- Institute of Physics
- Year
- 2006
- Tongue
- English
- Weight
- 752 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0957-4484
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## Abstract Reaction of an isocyanide with an iminium ion intermediate, formed by reaction between 6‐formyl‐2,3‐dimethoxybenzoic acid and secondary amines (dibenzyl‐ or benzyl(isopropyl)amine) in the presence of silica nanoparticles (silica NPs, __ca.__ 70 nm) proceeds smoothly at room temperature
## Abstract Multicomponent reaction of o‐formylbenzoic acid derivative (I) with secondary amines (III) and isocyanides (II) proceeds smoothly in the presence of silica nanoparticles under neat conditions to give dihydroisoindolone derivatives (IV) in good yields.