✦ LIBER ✦

Sulfur derivatives of 3-methyl-5-phenyl-1,2,4,3-triazaphosphole

✍ Scribed by Alfred Schmidpeter; Franz Steinmüller; Konstantin Karaghiosoff

Publisher: John Wiley and Sons
Year: 1994
Tongue: English
Weight: 403 KB
Volume: 5
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.520050410

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The triazaphosphole 1 adds sulfur along with HCl or H~2~S to yield, respectively, the dihydrotriazaphosphole thiochloride 4 and sesquisulfide 5 (two diastereomers). In pyridine solution, 1 adds sulfur alone to yield the trimer of a triazaphosphole monosulfide 7. Its central cyclotriphosphazane trisulfide ring has a trans structure and a boat conformation.

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