Sulfonation of alkenes with sulfur trioxide; stereospecific β-sultone formation

✍ Scribed by Bert H Bakker; Hans Cerfontain

• Publisher: Elsevier Science
• Year: 1987
• Tongue: French
• Weight: 266 KB
• Volume: 28
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)95398-x

✦ Synopsis

Sulfonation of I-octene, (E)-I-deuterio-1-octene, and (Z)-and (El-4-octene with one mol-equiv of sulfur trToxide yields the B-sultones Ta-d respectively. The reaction proceeds stereospecifically via a concerted ci&&addition.