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Sulfonation of alkenes with sulfur trioxide; reversible stereospecific β-sultone formation

✍ Scribed by Bert H. Bakker; Hans Cerfontain


Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
297 KB
Volume
30
Category
Article
ISSN
0040-4039

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Sulfonation of alkenes with sulfur triox
✍ Bert H Bakker; Hans Cerfontain 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 266 KB

Sulfonation of I-octene, (E)-I-deuterio-1-octene, and (Z)-and (El-4-octene with one mol-equiv of sulfur trToxide yields the B-sultones Ta-d respectively. The reaction proceeds stereospecifically via a concerted ci&&addition.