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Sulfonation of alkenes with an excess of sulfur trioxide; stereospecific formation of carbyl sulfates

✍ Scribed by Bert H Bakker; Hans Cerfontain


Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
223 KB
Volume
28
Category
Article
ISSN
0040-4039

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πŸ“œ SIMILAR VOLUMES


Sulfonation of alkenes with sulfur triox
✍ Bert H Bakker; Hans Cerfontain πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 French βš– 266 KB

Sulfonation of I-octene, (E)-I-deuterio-1-octene, and (Z)-and (El-4-octene with one mol-equiv of sulfur trToxide yields the B-sultones Ta-d respectively. The reaction proceeds stereospecifically via a concerted ci&&addition.

Sulfonation of 1- and 2-naphthol and the
✍ Harold R. W. Ansink; Erwin Zelvelder; Hans Cerfontain πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 467 KB

## Abstract The sulfonation of 1‐ and 2‐naphthol with sulfur trioxide in C^2^H~3~NO~2~ has been studied by using ^1^H NMR. 1‐Naphthol (1) yields, upon reaction with 1.0 mol‐equiv of SO~3~, a mixture of 2‐ and 4‐sulfonic acids (2‐ and 4‐S); upon increasing the reaction temperature, the relative amou