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Suitably designed chiral amino alcohols: synthesis, resolution and application to the catalytic enantioselective reduction of aryl alkyl ketones

✍ Scribed by I. Reiners; J. Martens

Publisher: Elsevier Science
Year: 1997
Tongue: English
Weight: 301 KB
Volume: 8
Category: Article
ISSN: 0957-4166
DOI: 10.1016/s0957-4166(96)00481-8

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✦ Synopsis

The amino alcohol rac-1-(1,2,3,4-tetrahydroisoquinoline-1-yl)-cyclopentanol was resolved via its O,O'-dibenzoyl-tartaric acid salt. These enantiomeric amino alcohols were used in the enantioselective reduction of prochiral aryl alkyl ketones. The resulting secondary alcohols were obtained in high enantiomeric excess.

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