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Suitable ligands for homogeneous ruthenium-catalyzed hydrogenolysis of esters

✍ Scribed by Marcel Chr. van Engelen; Herman T. Teunissen; Johannes G. de Vries; Cornelis J. Elsevier

Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
112 KB
Volume
206
Category
Article
ISSN
1381-1169

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4-Quinolylmethyl (4-QUI) esters of carboxylic acids and 1-naphthyimethyi (1-NAP) esters of carbonic and carbamic acids are reduced by palladium-catalyzed hydrogenolysis by formate anion. The reaction conditions are compatible with the presence of a benzyl ester and of an alkene double bond.