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Homogeneous transfer hydrogenolysis of carbon tetrachloride by carbinols catalyzed by dichlorotris(triphenylphosphine)ruthenium (II)

โœ Scribed by Yoel Sasson; Garry L. Rempel


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
150 KB
Volume
15
Category
Article
ISSN
0040-4039

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Homogeneous catalytic transfer-hydrogena
โœ Yoel Sasson; Jochanan Blum ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 185 KB

Dichlorotris(triphenylphosphine)ruthenium (II), RuC12(PPh3)3, is well known for its ability to catalyze hydrogen transfer in several organic reactions l-10 . We now wish to report the application of this effect to the selective transfer-hydrogenation of a&unsaturated carbonyl compounds. A mixture of