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Hydrogenolysis of triphenylphosphine coordinated to ruthenium (II) by hydrogen transfer from organic compounds

โœ Scribed by Takeshi Nishiguchi; Kazushige Tanaka; Kazuo Fukuzumi


Publisher
Springer
Year
1978
Tongue
English
Weight
135 KB
Volume
3
Category
Article
ISSN
0340-4285

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Homogeneous catalytic transfer-hydrogena
โœ Yoel Sasson; Jochanan Blum ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 185 KB

Dichlorotris(triphenylphosphine)ruthenium (II), RuC12(PPh3)3, is well known for its ability to catalyze hydrogen transfer in several organic reactions l-10 . We now wish to report the application of this effect to the selective transfer-hydrogenation of a&unsaturated carbonyl compounds. A mixture of