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Substrate selectivity and mechanism of oxidation of alkanes by peroxynitrous acid in aqueous solution

✍ Scribed by E. S. Rudakov; V. P. Tret’yakov; V. L. Lobachev; L. A. Min’ko; Ya. V. Matvienko; V. G. Popov

Publisher
Springer
Year
2006
Tongue
English
Weight
94 KB
Volume
42
Category
Article
ISSN
0040-5760

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The kinetics of oxidation of L-ascorbic acid (H2A) by the mononuclear complex [Co(NH3)5(OH2)] (C103) 3 have been studied spectrophotometrically at 490nm. The mechanism involves single one-electron transfers involving the pentaamminehydroxo complex and the ascorbate anions (HA-and A 2 ), subsequent f