With catalytic amounts of 2,2,6,6-tetramethyl-l-piperidinyloxy (TEMPO) and hypochlorite/bromide as the regenerating oxidant in water, primary alcohol groups in glucans and derivatives thereof were rapidly and completely oxidised. For pyranosides, selectivity was higher than 95% and no side products
Selective oxidation of primary alcohols mediated by nitroxyl radical in aqueous solution. Kinetics and mechanism
β Scribed by Arjan E.J. de Nooy; Arie C. Besemer; Herman van Bekkum
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 498 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
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