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Substitution reactions of binuclear square-prismatic complexes I. Kinetics and mechanism of the reaction of tetrapotassium octachloro-dimolybdate(II) with acetic acid

✍ Scribed by RolandJ. Mureinik

Book ID
116012853
Publisher
Elsevier Science
Year
1977
Weight
50 KB
Volume
54
Category
Article
ISSN
0022-5088

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πŸ“œ SIMILAR VOLUMES

Reaction mechanisms of binuclear complex
Reaction mechanisms of binuclear complexes containing a quadruple metalξ—Έmetal bond. The reaction of acetic acid with potassium octachlorodimolybdate(II)
✍ R.J. Mureinik πŸ“‚ Article πŸ“… 1977 πŸ› Elsevier Science 🌐 English βš– 758 KB

## The reaction of acetic acid with equilibriated solutions of tetrapotassium octachlorodimolybdate(II) in hydrochloric acid, p-toluenesulphonic acid (HPTS) and mixtures of these two acids has been studied. In HPTS the final product is tetrakisacetato-dimolybdenate( but in chloride-containing media

Kinetics and mechanisms of substitution
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## Abstract The activation energy parameters for the reaction of PdX (X=Cl^βˆ’^, Br^βˆ’^) in aqueous halide acid solution with thiourea (tu) and selenourea (seu) have been determined. High rates of reaction parallel low enthalpies and appreciable negative entropy of activation. The rate law in each cas