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Reaction mechanisms of binuclear complexes containing a quadruple metalmetal bond. The reaction of acetic acid with potassium octachlorodimolybdate(II)

✍ Scribed by R.J. Mureinik

Book ID: 104139495
Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 758 KB
Volume: 23
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)94749-2

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✦ Synopsis

The reaction of acetic acid with equilibriated solutions of tetrapotassium octachlorodimolybdate(II) in hydrochloric acid, p-toluenesulphonic acid (HPTS) and mixtures of these two acids has been studied. In HPTS the final product is tetrakisacetato-dimolybdenate( but in chloride-containing media mixed chloroacetato complexes are obtained. The reaction proceeds in two observable stages in all reaction media, and the kinetics of these two reactions have been measured. Both reactions are first order in

complex, and the observed rate laws are of the form k I KHL'O2Hl II A, +-4cl WI obs.1 = I t [CH,CO,H] W'l I k IWCO,Hl obs.2 = I+ /? [CH,

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