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Kinetics and mechanism of the reactions of mononuclear and binuclear ruthenium(III) ammine complexes with ascorbic acid

✍ Scribed by Akhtar, Mohammed J.; Haim, Albert


Book ID
126042886
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
411 KB
Volume
27
Category
Article
ISSN
0020-1669

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## Abstract The reduction of Fe(CN)~5~L^2βˆ’^ (L = pyridine, isonicotinamide, 4,4′‐bipyridine) complexes by ascorbic acid has been subjected to a detailed kinetic study in the range of pH 1–7.5. The rate law of the reaction is interpreted as a rate determining reaction between Fe(III) complexes and t