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Substitution of bridging S2 ligands in the [Nb2(μ-S2)2]4+ core: a simple route to [Nb2(Se2)2]4+, [Nb2(S)(Te2)]4+ and [Nb2(S)2]4+

✍ Scribed by Sokolov, Maxim; Imoto, Hideo; Saito, Taro; Fedorov, Vladimir


Book ID
121430415
Publisher
The Royal Society of Chemistry
Year
1999
Tongue
English
Weight
201 KB
Volume
1
Category
Article
ISSN
1472-7773

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Coordination Chemistry of [Nb2(S2)2]4+ C
✍ M. Sokolov; A. Virovets; W. Clegg 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB 👁 2 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space