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Synthesis and crystal structure of [Nb2(S1.72Se2.28)(S2CNEt2)4]—A solid solution based on [Nb2(μ2, η2-X2)2(S2CNEt2)4], where X2=S2, SSe, and Se2. New model of structure refinement of [Nb2(S2)2(S2CNEt2)4], where X2=S2, SSe, and Se2. New model of structure refinement of [Nb2(S2)2(S2CNEt2)4]

✍ Scribed by A. V. Virovets; M. N. Sokolov; N. V. Podberezskaya; V. E. Fedorov


Book ID
110563805
Publisher
SP MAIK Nauka/Interperiodica
Year
1996
Tongue
English
Weight
393 KB
Volume
37
Category
Article
ISSN
0022-4766

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Coordination Chemistry of [Nb2(S2)2]4+ C
✍ M. Sokolov; A. Virovets; W. Clegg 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 151 KB 👁 2 views

Bis(disulfido) bridged Nb IV cluster oxalate complexes [Nb 2 (S 2 ) 2 (C 2 O 4 ) 4 ] 4± were prepared by ligand substitution reaction from the aqua ion [Nb 2 (l-S 2 ) 2 (H 2 O) 8 ] 4+ and isolated as K 4 (3). The crystal structures of 1 and 2 were determined. The crystals of 1 belong to the space