The triplet--triplet absorption spectrum of naphthalene (3B1, -3B2u; 3A, -3B2u) was calculated using an ab initio method with a S T O -~G basis set and moderately large configuration interaction. Eight bands were found in the region 18,000-45,000 cm-' and compared with those of the experimental spec
Substitution effects on the triplet-triplet absorption spectrum of naphthalene
β Scribed by T.G Pavlopoulos
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- English
- Weight
- 406 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The polarization of the triplet-triplet (T-T) absorption spectrum of a-, p-hydroxynaphathalene and 2,3-dihydroxynaphthalene from 4000 to 6000 A wz~s measured. The obtained data were compared with theoretical ulcu~tions on T-T absorption spectra and polarization data on the lowest-energy singlet-singlet absorption bands of these compounds.
π SIMILAR VOLUMES
The polarized excitation spectrum of the triplet-triplet absorption of some hydrocarbons has been measured by the method of photoselection. Advantages offered by the polarized excitation spectrum for further polarization work are briefiy discussed.