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Substitution effects on the triplet-triplet absorption spectrum of naphthalene

✍ Scribed by T.G Pavlopoulos


Publisher
Elsevier Science
Year
1973
Tongue
English
Weight
406 KB
Volume
20
Category
Article
ISSN
0009-2614

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✦ Synopsis


The polarization of the triplet-triplet (T-T) absorption spectrum of a-, p-hydroxynaphathalene and 2,3-dihydroxynaphthalene from 4000 to 6000 A wz~s measured. The obtained data were compared with theoretical ulcu~tions on T-T absorption spectra and polarization data on the lowest-energy singlet-singlet absorption bands of these compounds.


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The triplet--triplet absorption spectrum of naphthalene (3B1, -3B2u; 3A, -3B2u) was calculated using an ab initio method with a S T O -~G basis set and moderately large configuration interaction. Eight bands were found in the region 18,000-45,000 cm-' and compared with those of the experimental spec

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