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Substituent-induced 13C chemical shifts of 3-substituted camphors

✍ Scribed by Carlos R. Kaiser; Ernani A. Basso; Roberto Rittner

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 69 KB
Volume: 39
Category: Article
ISSN: 0749-1581
DOI: 10.1002/mrc.875

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✦ Synopsis

Abstract

The complete ^13^C NMR analysis of 3‐substituted camphors with F, Cl, Br, I, OH, OMe, SMe, NHMe, NMe~2~ and Me substituents at endo and exo positions, and also the corresponding ‘oxo’ and dichloro derivatives, were obtained by 1D and 2D NMR techniques. The resulting substituent‐induced chemical shifts (SCS) for these difunctional systems show the influence of electronic and steric mechanisms. Copyright © 2001 John Wiley & Sons, Ltd.

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