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Substituent-induced chemical shift 13C NMR study of substituted 2-phenylthiazolidines

✍ Scribed by R. Umarani

Publisher
John Wiley and Sons
Year
1992
Tongue
English
Weight
183 KB
Volume
30
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The analysis of the ^13^C NMR chemical shifts of 16 substituted 2‐phenylthiazolidines shows that the 1,3‐thiazolid‐2‐yl group exerts a deshielding effect at the ipso carbon (C‐1′) and shielding effects at the ortho and para positions of the benzene ring (C‐2′ and C‐4′), and that the transmission of the resonance effect from the substituents in the phenyl ring to the benzylic carbon (C‐2) in the thiazolidine heterocycle is diminished by the polarizable nitrogen and sulphur atoms.

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