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Substituent effects on carbon-13 chemical shifts of para-substituted benzylbenzenes

✍ Scribed by Yoshimi Nakai; Tetsuo Takabayashi; Fukiko Yamada

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
234 KB
Volume
13
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Carbon‐13 chemical shifts of fourteen para‐substituted benzylbenzenes have been determined. The relative substituent chemical shifts (SCS) of the methylene carbons and the aromatic ring carbons (C‐4, C‐1′ and C‐4′) correlated well with the Hammett substituent effects using the dual substituent parameter method. The transmission of substituent effects through the benzylbenzene system is briefly discussed.

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