✦ LIBER ✦

Substituent field effects on the regiochemistry of the ene reaction

✍ Scribed by Clennan, E. L.; Koola, Jaya J.

Book ID: 126776549
Publisher: American Chemical Society
Year: 1993
Tongue: English
Weight: 224 KB
Volume: 115
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00062a067

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

A comparison of substituent field effect

A comparison of substituent field effects on the regiochemistry of the ene reactions of allylic sulfides and ethers

✍ Edward L. Clennan; Jaya J. Koola; Ming-Fang Chen 📂 Article 📅 1994 🏛 Elsevier Science 🌐 French ⚖ 848 KB

## Abstracts The reactions of 4-methyl-1,2,4-t with allylic ethers aad ftdidea have beea examhd. The diffemt mspowes of the regicchemistty io the two mctio: sea-k4 to changty in the eleetroaic charam of the

The effect of the trimethylsilyl group o

The effect of the trimethylsilyl group on the regiochemistry of the ene reaction

✍ Frederick E. Ziegler; Koichi Mikami 📂 Article 📅 1984 🏛 Elsevier Science 🌐 French ⚖ 210 KB

Our interest in the tandem Claisen-ene rearrangement' and the desire to develop efficient methods for the control of both the regio-and stereochemistry of the ene reaction for eventual applications in organic synthesis led us to explore the role of the trimethylsilyl group as a controlling unit. I?

Photooxygenation of vinyl sulfides: Subs

Photooxygenation of vinyl sulfides: Substituent effects on the [2+2] cycloaddition versus schenck ene reaction modes

✍ Waldemar Adam; A. Sampath Kumar; Chantu R. Saha-Möller 📂 Article 📅 1995 🏛 Elsevier Science 🌐 French ⚖ 144 KB

The influence of water on substituent fi

The influence of water on substituent field effects

✍ Cai Jinfeng; Ronald D. Topsom 📂 Article 📅 1990 🏛 Elsevier Science 🌐 English ⚖ 416 KB

The effect of styrene α-substituents on

The effect of styrene α-substituents on the regiochemistry of [2+2] cycloadditions with difluoroallene.

✍ William R Dolbier Jr.; Mark Seabury 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 109 KB

## Consistent with our hypothesis for a mechanism involving two kinetically-distinct diradical intermediates, the observed effects of styrene a-substituents can be explained as deriving either from steric effects or radical stabilizing effects.

An unusual effect of selenium substituen

An unusual effect of selenium substituents on the regiochemistry of a baeyer-villiger rearrangement

✍ Barry M. Trost; Peter Buhlmayer; Michael Mao 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 201 KB

The regioselectivity of a Baeyer-Villiger oxidation of a cyclobutanone is dependent upon the oxidation state of a proximal selenium substituent. for the selenium dioxide-hydrogen peroxide oxidation of ketones. Sharpless, K. B. ; Gordon, K.M. J. Am. Chem. Soq . 1976, 98, 300. 9. It can be argued that