✦ LIBER ✦

The effect of styrene α-substituents on the regiochemistry of [2+2] cycloadditions with difluoroallene.

✍ Scribed by William R Dolbier Jr.; Mark Seabury

Book ID: 104233426
Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 109 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)81023-6

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✦ Synopsis

Consistent with our hypothesis

for a mechanism involving two kinetically-distinct diradical intermediates, the observed effects of styrene a-substituents can be explained as deriving either from steric effects or radical stabilizing effects.

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