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Substituent effect on the mechanism of 2+2 cycloadditions

โœ Scribed by M. Duran; J. Bertran


Book ID
118065847
Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
320 KB
Volume
107
Category
Article
ISSN
0166-1280

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The effect of styrene ฮฑ-substituents on
โœ William R Dolbier Jr.; Mark Seabury ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 109 KB

## Consistent with our hypothesis for a mechanism involving two kinetically-distinct diradical intermediates, the observed effects of styrene a-substituents can be explained as deriving either from steric effects or radical stabilizing effects.