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The influence of water on substituent field effects

โœ Scribed by Cai Jinfeng; Ronald D. Topsom

Book ID
113257095
Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
416 KB
Volume
204
Category
Article
ISSN
0166-1280

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Transmission of substituent effectsโ€”a CN
Transmission of substituent effectsโ€”a CNDO approach. The influence of the internal electric field on the 29Si NMR substituent chemical shifts of phenyltrimethylsilanes and phenoxytrimethylsilanes
โœ Renate Wolff; Reiner Radeglia; Robert Ponec ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 190 KB

## Abstract The ^29^Si NMR subtituent chemical shifts of 14 __meta__โ€and __para__โ€substituted derivatives of phenyltrimethylโ€and phenoxytrimethylโ€silanes have been interpreted in a uniform manner. They are shown to depend not only on the local but also on the nonโ€local parts of the charge distribut